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Oxidation number of K +4 4 (oxidation number of oxygen) + oxidation . . Calculate the molar mass of potassium permanganate (KMn O4). These cookies help provide information on metrics the number of visitors, bounce rate, traffic source, etc. As a result, the total oxidation number of all atoms in KMnO4 equals zero. However, you may visit "Cookie Settings" to provide a controlled consent. The reason is that the molar mass of the substance affects the conversion. For 2H2O we have four H atoms (the coefficient 2 times the subscript 2) and two O atoms.For compounds with parenthesis, like Ca(NO3)2, we multiple the atoms inside the parentheses by the subscript. 0 mol. Consider this question: What is the molarity of KMnO4 in a solution of 0.0908g of KMnO4 in 0.500L of solution? The equations representing oxidation in these media are In acidic medium 2KMnO 4 + H 2 SO 4 K 2 SO 4 + 2MnSO 4 + 3H 2 O + 5 [O] MnO 4- + 8H + + 5e - Mn 2+ + 4H 2 O In neutral or alkaline medium We are NOT chemists, but Math nuts!!!!. Describe the following movement: extension. Compute Mass of Each Element. Correct answer - What changes in color occur when bromine and kmno4 reacts with an alkene? I was exposed to contagious dumbness. Answer link KMnO4 also oxidizes phenol to para-benzoquinone. number of moles by the molar mass of glucose (180 g/mol): 0 mol x 180. What is the load current when the triac is conducted? In general, One mole of any element contains 6.022 1023 atoms of that element. How many moles of HCl are present in 500 mL of 0 M HCl solution? O (Oxygen) STEP 1: Write the correct formula STEP 2: Determine the molar mass STEP 3: Use dimensional analysis to convert HOW TO COUNT ATOMS Background+Information:+ subscripts!-!the!little!numbers!thattell!how!many!atoms!there!are!! In permanganate anion (MnO4-) the manganese atom is bonded with four oxygen atoms through three double bonds and one single bond. How many oxygen atoms are in 225 g of KMnO4? How many moles of oxygen atoms does this represent? 4 answers Pick a number. How many atoms of hydrogen are in 100 g of methane? Both the same number on the periodic table, you just need to change the units (g/mol -vs- amu) Given 12 g of aluminum, how many moles do you have? This cookie is set by GDPR Cookie Consent plugin. Ive never given a wrong answer -- even in the most adverse of conditions, so the risk is minimal Im sure. Of course many on here do, so its not really definitive, its just a birds of a feather kind of relation. Guest Jan 14, 2016 5 Answers #1 +5 Best Answer In this case we have two H atoms so we multiply 2 x 6.02 x 10^23.Finding the number of atoms in Potassium permanganate Under harsher conditions, the dione is cleaved to form two carboxylic acids. Oxidation of Organic Molecules by KMnO4 is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by LibreTexts. The cookie is set by the GDPR Cookie Consent plugin and is used to store whether or not user has consented to the use of cookies. P.S. 75 g KMnO4 = molecules KMnO4 B. How many grams of potassium permanganate KMnO4 are in 2.55 moles? Examples of carbons that are not oxidized. Most minerals that contain potassium are referred to as potash. We use cookies on our website to give you the most relevant experience by remembering your preferences and repeat visits. There are 6.022 1023 atoms of potassium in every mole of potassium. Six. If a question is ticked that does not mean you cannot continue it. Using the chemical formula of the compound and the periodic table of elements, we can add up the atomic weights and calculate molecular weight of the substance. Use dimensional analysis to calculate the number of O atoms in 1.4238 mol KMnO4. How many atoms is in potassium? The cookie is used to store the user consent for the cookies in the category "Other. Is kmno4 an acid or base? The molar mass of an element is the mass in grams of one mole of the element, which is its relative atomic mass (atomic weight) on the periodic table in g/mol. Scott Becker began writing professionally in 2008. : an American History (Eric Foner), Civilization and its Discontents (Sigmund Freud), Forecasting, Time Series, and Regression (Richard T. O'Connell; Anne B. Koehler), Biological Science (Freeman Scott; Quillin Kim; Allison Lizabeth), Campbell Biology (Jane B. Reece; Lisa A. Urry; Michael L. Cain; Steven A. Wasserman; Peter V. Minorsky), Chemistry: The Central Science (Theodore E. Brown; H. 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It is a common oxidizing agent often used in titrations due to its color and redox potential. Solution: Calculate the mass of ethylene glycol (C2H6O2) needed to prepare 500 mL of a 20% 2!is!the!subscript . 1 mole is equal to 1 moles KMnO4, or 158.033949 grams. It is still sometimes used for this purpose, along with other chemicals, especially when preparing black-and-white photographs. Previous. Alkanes and aromatic compounds do not react with potassium permanganate. Why SJF Cannot be implemented practically? Science Chemistry. NaCl , we have 3.0 moles of Na+. How many sodium ions are in 3.0 moles of NaCl? How many moles of Oxygen are contained in 2.50 mol of KMnO4??? Finally, when no hydrogens are present on the benzylic carbon, no reaction occurs (example 4). In this case, there are 14 total atoms in one formula unit of (NH 4) 2 CO 3 (two N, eight H, one C and three O). Q: The concentration of a dilute aspirin solution is 0.000530 M 0.000530 M . . A: Calculation of molar mass of C8H9O4: The atomic mass of C = 12.010 g/mol The atomic mass of H = Q: How many carbon atoms are present in a mole of 12C? So, the equivalent weight of K M n O X 4 is molecular weight 5 And in example 3, two benzoic acids are formed. Potassium permanganate has the chemical formula KMnO4, where the "4" is a subscript below oxygen. How many moles are in KMnO4? Instead it is found in various minerals such as sylvite, carnallite, langbeinite, and kainite. Molecular weight of KMnO4 is [39+65+(164)]= 158grams. 9) What is the total number of atoms in 0.139 mol of Fe(OH263-? 91024 hydrogen atoms . The chemical formula of potassium permanganate (KMnO4) indicates that one mole of the compound contains four moles of O atoms. . How many moles of HCl are present in 500 mL of 0 M HCl solution? Which solution, 0.50M or 0.25M, will be darker in tone? Multiply in writing. How many moles are in 4.9 x 1023 molecules of ZnCl2? b) Describe a change you can make to basketball to allow the game to be played on the Moon. Size and Color. This is reduced to 2+ when a reducing agent, such as oxalate ion, is present. Necessary cookies are absolutely essential for the website to function properly. and a -1 permanganate (polyatomic) anion (MnO4) Mn(VII) is reduced under acidic conditions to Mn(IV) or Mn(II) according to the half-reactions shown below, with the indicated cell potentials1, \[MnO_4^- + 4H^+ + 3e^- \rightarrow MnO_2 + 2H_2O\;\;\;\;E^o = 1.68\,V\], \[MnO_4^- + 8H^+ + 5e^- \rightarrow Mn^{2+} + 4H_2O\;\;\;\;E^o = 1.5\, V\], \[MnO_4^- + 2H_2O + 3e^- \rightarrow Mn^{2+} + 4OH^-\;\;\;\;E^o = 0.6\, V\], KMnO4 is able to oxidize carbon atoms if they contain sufficiently weak bonds, including. KMnO 4 is able to oxidize carbon atoms if they contain sufficiently weak bonds, including. The reaction only works if there is at least one hydrogen attached to the carbon. KMnO4 molecular weight Molar mass of KMnO4 = 158.033949 g/mol This compound is also known as Potassium Permanganate. How does alkene react with KMnO4? 50 mL. Youre not deadly enough to be him, but you have a comparable lack of chemistry skills. For example, H2 means there are two Hydrogen atoms.When there is no number after an element, we assume there to be one atom of that element. You are right about the not a chemist part . When alkaline KMnO4 is treated with KI, iodide ion is oxidised to IO 3-. Basketball requires quick starts and stops and quick changes in direction. Now, in order to calculate the equivalent mass of K M n O X 4, first I need to calculate it's n -factor which turns out to be 5 because the oxidation state of M n in K M n O X 4 is + 7 whereas in M n C l X 2 it is + 2. How many molecules are in 110g of diphosphorus pentoxide? A: Click to see the answer. Calculate the number of moles in 674.65 g of C7HsN3O6. Calculate the number of moles of potassium permanganate (KMnO_4) corresponding to 220.0 g of. How many moles are in 25.0 grams of KMnO4? Potassium permanganate can help to treat both bacterial and fungal skin infections such as athletes foot and impetigo. Thanks for the generous compliment. Advertisement cookies are used to provide visitors with relevant ads and marketing campaigns. Convert grams KMnO4 to moles or moles KMnO4 to grams Molecular weight calculation: 39.0983 + 54.938049 + 15.9994*4 Percent composition by element Calculate the molecular weight of a chemical compound Enter a chemical formula: It's a word that represents an amount or a number, Which contains more atoms, a mole of copper or a mole of gold? A. These cookies will be stored in your browser only with your consent. Calculate the molarity of H2C2O4 and KMnO4. How can we avoid the occurrence of weld porosity? permanganate, but the permanganate stays together as MnO4, Permanganate is an ion which has the formula of MnO4^-, MnO4 2- OR MnO4 -2(both are the same things, The oxidation number if Mn in the MnO4- ion is 7. (write down # in each one), Which weighs more, a mole of copper or a mole of gold? And the n -factor of H C l is 1. Exercise's 1 No of moles of sodium atoms = 2x6- 75 = 13.5 No of modes of sulphur atoms = 1X6. Chemistry The Mole Concept The Mole 1 Answer anor277 Nov 15, 2016 Number of moles = Mass Molar mass Explanation: And moles of potassium permanganate = 23.7 g 158.03 g mol1 1 6 mol. A common request on this site is to convert grams to moles. (ex:!In!3H 2O,!the! Given 125 g ofH2SO4, how many moles do you have? The products that are obtained can vary depending on the conditions, but because KMnO4 is such a strong oxidizing agent, the final products are often carboxylic acids. 1 Mn (Manganese) b-How many atoms are there is 20.0 grams of calcium? The potassium ion in KMnO4 has a permanent oxidation state of 1+, and the oxygen atoms each have a permanent oxidation state of 2-. The oxidation of alkyl side-chains to form benzoic acids was historically used in qualitative analysis to determine the positions of alkyl groups in substituted aromatic systems. Accessibility StatementFor more information contact us atinfo@libretexts.orgor check out our status page at https://status.libretexts.org. The percentage by weight of any atom or group of atoms in a compound can be computed by dividing the total weight of the atom (or group of atoms) in the formula by the formula weight and multiplying by 100. The formula indicates that there is 1 mole K, 1 mole Mn, and 4 moles O per mole of KMnO4. Nauseated, since you are such a 'genius' [interprete as 'know-it-all' ] why don't you just answer the question!! KMnO4 will dissolve in water to give a deep purple (wine) The small number after the element symbol is called the subscript and this tells us how many of that atom are in the compound. See Answer 1 grams KMnO4 is equal to 0.0063277542979072 mole. This compound is also known as Potassium Permanganate. set-up. Each has a single positive and single negative charge, respectively. A) 19.0 B) 2.64 98.37. La estatua - prlogo, La estatua, captulo 1, Don Buckley, Kathryn Thornton, Michael Padilla, Michael Wysession, Zipporah Miller. If I gave a wrong answer, someone (you) might troll me and that looks bad on my permanganate (permanent) record. This figure is obtained by adding the individual molar masses of four oxygen atoms, one manganese atom and one potassium atom, all available on the Periodic Table of the Elements (see the Additional Resources section). Aluminum sulfate has a molecular weight of 342.15 grams per mole. The oxidation state of manganese in this salt is +7. Balancing the reactions would involve using the methods learned in general chemistry, requiring half reactions for all processes. At the time, its main use was in photography since its staining potential can be used in the development of slides. volume of the solution (in liters) by the concentration of the solution: 0 L x P = 2 atoms. do you have? Carbon atoms with weak C-H bonds, such as. . Cross), The Methodology of the Social Sciences (Max Weber), Principles of Environmental Science (William P. Cunningham; Mary Ann Cunningham), Psychology (David G. Myers; C. Nathan DeWall), Brunner and Suddarth's Textbook of Medical-Surgical Nursing (Janice L. Hinkle; Kerry H. Cheever), Give Me Liberty! Perhaps this wouldpresent a problem for you? The cookie is set by GDPR cookie consent to record the user consent for the cookies in the category "Functional". Where should I start working out out of shape? x mol Answer to correct significant figures x mol (c) How many milliliters of 10.6 M HCI solution are needed to obtain 0.205 mol of HCI? ANSWER:- we know that atomic mass of Si atom is 28.08 from periodic table and one mole of Si atom is 6.023 * 10 23 (Avagadro's number) atoms of Si that is,. have? How to find the oxidation number for MN in KMnO4? KMnO4)(6.022 X 1023/1 mole Mn)(1 mole Mn atoms/6.022 X 1023) Using the principles above, we expect KMno4 to react with alkenes, alkynes, alcohols, aldehydes and aromatic side chains. Molar mass of KMnO4 = 158.034 g/mol In the molecule of KMnO4 there are 4 atom O 1 mole of KMnO4 ~ 4 mol of O Mol of O = (4 x 16 g/mol)/158.034 g/mol = 0.405 mol of O ~ x 0.405 mol of KMnO4 = 0.1 mol of KMnO4. Multiply the number of atoms by the atomic weight of each element found in steps 1 and 2 to get the mass of each element: Mass (g/mol) K (Potassium) 1 39.0983 = 39.0983. Calculate the molar mass of potassium permanganate (KMnO4). Q: JUllent in rhubarb found to have anti-tumor properties. d-Calculate the mass in grams of one calcium atom. 75 - 6.75 No of moles of oxygen atoms = 4X6. Given 34 moles CF4 , how many grams would you have? Out of these, the cookies that are categorized as necessary are stored on your browser as they are essential for the working of basic functionalities of the website. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. a. What is the role of KMnO4 in oxidation reaction? Potassium permanganate has a molar mass of 158.04 g/mol. P.S. 2% KMnO4solution (a purple solution) is added dropwise and the solution is shaken. For example, H2 means there are two Hydrogen atoms.If we add up all of the atoms for AgNO3 we well find that we have a total of 5 atoms for Silver nitrate .When there is no number after an element, we assume there to be one atom of that element. Potassium permanganate, KMnO4, is a powerful oxidizing agent, and has many uses in organic chemistry. Therefore, 40g of KMnO4 contains 5515840, which is equal to 14 grams of potassium. common chemical compounds. Functional cookies help to perform certain functionalities like sharing the content of the website on social media platforms, collect feedbacks, and other third-party features. 4 O ( Oxygen ) Determine the percent composition of KMnO4. Primary alcohols such as octan-1-ol can be oxidized efficiently by KMnO4, in the presence of basic copper salts.3 However, the product is predominantly octanoic acid, with only a small amount of aldehyde, resulting from overoxidation. x mL Answer . Name the . 0 mol/L = 0 mol. The potassium ion in KMnO4 has a permanent oxidation state of 1+, and the oxygen atoms each have a permanent oxidation state of 2-. For 2H2O we have four H atoms (the coefficient 2 times the subscript 2) and two O atoms.For compounds with parenthesis, like Ca(NO3)2, we multiple the atoms inside the parentheses by the subscript. 0.124 mol KMnO4 0.158 mol KMnO4 0.199 mol KMnO4 0.316 mol KMnO4 Get the answers you need, now! We use the most common isotopes. volume of the solution (in liters) by the concentration of the solution (20% or 0) The answer is 158.033949. The small number after the element symbol is called the subscript. Legal. These cookies ensure basic functionalities and security features of the website, anonymously. The number of molecules is therefore 6.022*10 23 * 55.556 = 3.346*10 25 molecules. one, so you do not need to go all the way in this, a formal How many atoms of potassium are in KMnO4? How to calculate the molar mass of potassium dichromate? Next > . For example, in H2O we have only one Oxygen atom since there isnt a number after the O.If there is a number in front of the compound (its called a coefficient), like 2H2O that means we have two separate molecules. 16.1201 grams KMnO4 (1 mole KMnO4/158.04 grams)(1 mole Mn/1 mole Why alkane cannot be oxidized with kmno4 solution? 1 mole is equal to 1 moles Potassium Permanganate, or 158.033949 grams. Medium. ---------------------------------------------------- Correct option is E) Following atoms are present in the given formula: Ca = 3 atoms. 1 CHE101 - Summary Chemistry: The Central Science, Dr. Yost - Exam 1 Lecture Notes - Chapter 18, 1.1 Functions and Continuity full solutions. Molecular weight of KMnO4=158.034 g/mol 2.50 X 158.034=395.085 Since molecular weight of Oxygen=15.9994g/mol, therefore, 395.085/15.9994=24.694 moles of Oxygen. How do you calculate potassium permanganate? In neutral medium KMnO4 forms MnO2 (+7 to +4) i.e. volume of the solution (in liters) by the concentration of the solution: 0 L x 0. Downing, Donald T.; Greene, Richard S., Journal of Investigative Dermatology (1968), 50(5), 380-6. How many atoms of each element are present in KMnO4? The cookies is used to store the user consent for the cookies in the category "Necessary". Mass of KMnO4 2 Multiply the atomic weight of each element with its number of atoms present in the compound. Q: A Redox Titration Is Performed To Determine The Concentration Of A Potassium Permanganate Solution (KMnO4) Using Sodium Oxalate (Na2C20.) Equivalent weight = Molar weight / Number of electrons that take . If the formula used in calculating molar mass is the molecular formula, the formula weight computed is the molecular weight. 5 More answers below Trevor Hodgson How many molecules are in 0.83 moles of HCl? When this dissociates in water, the K separates from the Molecular mass of KMnO4 = 39.1 + 54.9 + 4(16.0) = 158.0 If you have 0.00812 mol of H2CO3, how many molecules Although overoxidation is less of a problem with secondary alcohols, KMnO4 is still not considered generally well-suited for conversions of alcohols to aldehydes or ketones. As a result, the molecule has no overall charge. O = (4 2) 8 atoms. 34 x 6 - 02 2x1023 ) Formula we Is = 1 408 x102 Formula units 3) gn 1 mol Nars, there as one . To find the total number of atoms in KMnO4 (Potassium permanganate) well add up the number of each type of atom. Formula weights are especially useful in determining the relative weights of reagents and products in a chemical reaction. It is also known as Condys crystals or permanganate of potash. The potassium cation is a spectator ion and generally does not react. In one mole of matter, there is precisely 6. Other uncategorized cookies are those that are being analyzed and have not been classified into a category as yet. By performing the necessary multiplications, the calculation is given as Al atoms =2 x1, S atoms = 3 x1 and O atoms = 3 x 4. How many milligrams would the unknown sample weigh? 2023 Leaf Group Ltd. / Leaf Group Media, All Rights Reserved. pdf, EMT Basic Final Exam Study Guide - Google Docs, Test Bank Chapter 01 An Overview of Marketing, NHA CCMA Practice Test Questions and Answers, Sample solutions Solution Notebook 1 CSE6040, CHEM111G - Lab Report for Density Experiment (Experiment 1), Leadership class , week 3 executive summary, I am doing my essay on the Ted Talk titaled How One Photo Captured a Humanitie Crisis https, School-Plan - School Plan of San Juan Integrated School, SEC-502-RS-Dispositions Self-Assessment Survey T3 (1), Techniques DE Separation ET Analyse EN Biochimi 1, Laboratory Methods in Organic Chemistry (Chem 347). (4x16 g/mol) = 158 g/mol. Copyright 2023 MassInitiative | All rights reserved. Given 14.05 g of SO 2, how many molecules is this? The small number after the element symbol is called the subscript and this tells. contains 5.0 x 1022 atoms of carbon, how many molecules of sucrose are present in . Indications of a positive test: But opting out of some of these cookies may affect your browsing experience. In this case we would have two N atoms and six O atoms. Convert grams KMnO4 to moles or moles KMnO4 to grams, Molecular weight calculation: How many grams are in a mole of potassium permanganate? and the density of ethylene glycol (1.11 g/mL): 0.5 L x 0.2 x 1.11 g/mL = 0.111 g. number of moles by the molar mass of glucose (180.16 g/mol): 0.1 mol x 180.16, Calculate the volume of 0.1 M HNO3 solution r, Business Law: Text and Cases (Kenneth W. Clarkson; Roger LeRoy Miller; Frank B. Metal ions possess the electron in KMnO4 and thus the transition of charge takes place from O to Mn+. coloured solution. The word potassium stems from the English pot ash, which was used to isolate potassium salts. A: To answer: 1) Modify the given molecule to show the product of the oxidation reaction using NAD+ as. (write down how much each one weighs), = Mass of 1 mol (6.02 x 10 23) of a substance (g/mol). Browse the list of How many atoms are present in 175 g of element (b)? 1024 10) How many carbon atoms are there in 52.06 g of . This cookie is set by GDPR Cookie Consent plugin. Note that Avogadro's number is actually over itself in a form of Since the reaction between NaOH and HNO3 is 1:1, the Calculate the molar mass of potassium permanganate (KMnO4). You also have the option to opt-out of these cookies. We therefore we multiple the subscript for each element by the number in front. KMnO4 is an inorganic chemical compound. This website uses cookies to improve your experience while you navigate through the website. Potassium is a metal that belongs to the alkali family. 39.0983 + 54.938049 + 15.9994*4. (oxygen is So, n-factor= 3. The transition occurs when the chemical is in the presence of light. a) Describe how a basketball game will be affected by the decreased friction on the Moon. atoms of Oxygen. The formula weight is simply the weight in atomic mass units of all the atoms in a given formula. -2). There is only one Ca atom.Finally, if you are asked to find the number of atoms in one mole, for example, the number of H atoms in one mole of H2O, you multiply the number of atoms by Avogadros number. The number of atoms is 3 times larger because each molecule has three atoms, so there are 1.0038*10 26 atoms in a liter of water. Carbon atoms with bonds, as in alkenes and alkynes. Alkanes are called saturated hydrocarbons because each carbon is bonded with as many hydrogen atoms as possible. When reduced by another chemical, it loses its distinctive pink-purple color and becomes colorless. 110 g 1 mole 6.02 x 1023 molecules = 4.7 x 1023 molecules 142 g 1 mole Try: Make the following mole conversions. For the total, simply count up how many atoms are in the formula unit. { Oxidation_of_Organic_Molecules_by_KMnO4 : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()" }, { Addition_Reactions : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Chan_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Elimination_Reactions : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Free_Radical_Reactions : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Introduction_to_Bioconjugation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Keck_Asymmetric_Allylation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Named_Reactions : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Organic_Reactions : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Oxidation_and_Reduction_Reactions : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Pericyclic_Reactions : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Reaction_Fundamentals : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Reactivity : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Reactivity_of_Alpha_Hydrogens : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Rearrangement_Reactions : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Substitution_Reactions : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "Zimmerman-Traxler_Model" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()" }, [ "article:topic", "showtoc:no", "license:ccbyncsa", "licenseversion:40" ], https://chem.libretexts.org/@app/auth/3/login?returnto=https%3A%2F%2Fchem.libretexts.org%2FBookshelves%2FOrganic_Chemistry%2FSupplemental_Modules_(Organic_Chemistry)%2FReactions%2FOxidation_and_Reduction_Reactions%2FOxidation_of_Organic_Molecules_by_KMnO4, \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}}}\) \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash{#1}}} \)\(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\) \(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\)\(\newcommand{\AA}{\unicode[.8,0]{x212B}}\), The half-reaction and oxidation potential, General Reactivity with Organic Molecules, Reactions with Specific Functional Groups, http://www.epa.gov/ogwdw/mdbp/pdf/alter/chapt_5.pdf, http://www.masterorganicchemistry.coboxylic-acids/, status page at https://status.libretexts.org, Carbon atoms with weak C-H bonds, such as, C-H bonds in the alpha-positions of substituted, C-H bonds in carbon atoms containing C-O bonds, including, Carbons with exceptionally weak C-C bonds such as, C-C bonds next to an aromatic ring AND an oxygen, Aliphatic carbons (except those alpha to an aromatic ring, as above), Aromatic carbons (except phenol, as above), Carbons without a C-H bond, except as in (3) above, Abiko, Atsushi; Roberts, John C.; Takemasa, Toshiro; Masamune, Satoru, Tetrahedron Letters (1986), 27(38), 4537-40.